The configuration of the server is incomplete. Try executing those:
Defaults write NSGlobalDomain LSAdaptor PostgreSQL
Defaults write NSGlobalDomain LSModelName OpenGroupware.org_PostgreSQL
Note that this should not happen anymore with OGo 1.0a releases. Always ensure that your database server is running using:
psql -h localhost OGo OGo
(replace the first OGo with the database containing the OGo database schema and the second OGo with the user you use to connect PostgreSQL)