To enable LDAP authentication you need to set at least these defaults:
Defaults write NSGlobalDomain \ LSAuthLDAPServer '"myserver.de"' Defaults write NSGlobalDomain \ LSAuthLDAPServerRoot '"dc=opengroupware,dc=org"'
This makes OGo use a simple bind (ldapsearch -x) against the LDAP server to check credentials. OGo currently uses LDAPv2 for maximum interoperability.
Note that with LDAP authentication enabled OGo still needs to create an account record in the PostgreSQL database. This is done when a user logs in the first time and was successfully authenticated by LDAP (the user is taken to a welcome-page where he can decide whether to proceed).